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Polycyclic aromatic hydrocarbons (PAHs), also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons, are potent atmospheric pollutants that consist of fused aromatic rings and do not contain heteroatoms or carry substituents. Naphthalene is the simplest example of a PAH. PAHs occur in oil, coal, and tar deposits, and are produced as byproducts of fuel burning (whether fossil fuel or biomass). As a pollutant, they are of concern because some compounds have been identified as carcinogenic, mutagenic, and teratogenic. PAHs are also found in cooked foods. Studies have shown that high levels of PAHs are found, for example, in meat cooked at high temperatures such as grilling or barbecuing, and in smoked fish. They are also found in the interstellar medium, in comets, and in meteorites and are a candidate molecule to act as a basis for the earliest forms of life. In graphene the PAH motif is extended to large 2D sheets
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Polycyclic aromatic hydrocarbons (PAHs), also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons, are potent atmospheric pollutants that consist of fused aromatic rings and do not contain heteroatoms or carry substituents. Naphthalene is the simplest example of a PAH. PAHs occur in oil, coal, and tar deposits, and are produced as byproducts of fuel burning (whether fossil fuel or biomass). As a pollutant, they are of concern because some compounds have been identified as carcinogenic, mutagenic, and teratogenic. PAHs are also found in cooked foods. Studies have shown that high levels of PAHs are found, for example, in meat cooked at high temperatures such as grilling or barbecuing, and in smoked fish. They are also found in the interstellar medium, in comets, and in meteorites and are a candidate molecule to act as a basis for the earliest forms of life.  
  
  
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== Non - ligninolytic fungi ==
 
== Non - ligninolytic fungi ==
  
[[cytochrome P450 monooxygenase]] 와 [[epoxide hydrolase]] 에 의해 trans-dihydrodiol 을 형성하거나 비효소적인 재배열을 통해
 
 
Phenol  이 되고 , conjugate 를 형성 한다 .
 
 
몇 몇 fungi 는 ''trans''-dihydrodiol 과 Phenol을 sulfation , methylation 이나 glucose,xylose,glucuronic acid 와의 conjugation 을 통해
 
대사 시킬수 있다.
 
 
 
*Acenaphthene : C.elegans 에 의해 6-hydroxyacenaphthenone, 1,2-acenaphthenedione, trans -1,2-dihydroxyacenaphthene, cis 1,2-dihydroxyacenaphthene으로 대사 되어진다.
 
 
 
*Fluorene : C.elegans 에 의해 9-fluorenol , 9 -fluorenone ,2-hydroxy-9-fluorenone 으로 대사 되며 , 그외 여러 fungi 도 fluorene 을 산화 시킬수 있다. (Fluorene -> 9-Fluorenol ->9-Fluorenone -> 2- Hydroxy- 9 - fluorenone )
 
 
 
*Anthracene : ''C.elegans'' 에 의해 anthracene ''trans'' -1,2 - dihydrodiol enantiomer 와 1-anthryl sulfate 로 대사 되며 이외에 ''Rhizoctonia solani'',
 
''Cryphonectria parasitica'' , ''Rhizopus arrhizus'' ,''C.echinulata'' ,''Cladosporium herbarum''에 의해 대사 되어 진다고 알려져 있다 .
 
 
 
===알려진 그룹 ===
 
 
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참고
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Reference
 
Potential of Penicillium Species in the Bioremediation
 
Potential of Penicillium Species in the Bioremediation
  
 
==Ligninolytic fungi(nutrient-limited) ==
 
==Ligninolytic fungi(nutrient-limited) ==
  
Extracellular lignolytic enzyme에 의한 non specific radical oxidation 에 의해 분해된다.  
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Lignolytic fungi degrade PAHs trough non specific radical oxidation by Extracellular lignolytic enzymes.
 
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* Extracellular lignolytic enzyme
 
* Extracellular lignolytic enzyme
 
::*[[Lignin peroxidase]]
 
::*[[Lignin peroxidase]]
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[[file:Ligninolytic fungi.png| 600px]]
 
[[file:Ligninolytic fungi.png| 600px]]
  
출처 :Fungal metabolism of polycyclic aromatic hydrocarbons: past,
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reference :Fungal metabolism of polycyclic aromatic hydrocarbons: past,
 
present and future applications in bioremediation
 
present and future applications in bioremediation
  
=== 알려진 group ===
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=== Known species  ===
  
 
* ''Phanerochaete chrysosprium''
 
* ''Phanerochaete chrysosprium''

Latest revision as of 16:31, 8 April 2013

Contents

Polycyclic aromatic hydrocarbons (PAHs), also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons, are potent atmospheric pollutants that consist of fused aromatic rings and do not contain heteroatoms or carry substituents. Naphthalene is the simplest example of a PAH. PAHs occur in oil, coal, and tar deposits, and are produced as byproducts of fuel burning (whether fossil fuel or biomass). As a pollutant, they are of concern because some compounds have been identified as carcinogenic, mutagenic, and teratogenic. PAHs are also found in cooked foods. Studies have shown that high levels of PAHs are found, for example, in meat cooked at high temperatures such as grilling or barbecuing, and in smoked fish. They are also found in the interstellar medium, in comets, and in meteorites and are a candidate molecule to act as a basis for the earliest forms of life.



  • PAHs 의 구조

wikipedia:http://en.wikipedia.org/wiki/Polycyclic_aromatic_hydrocarbon

[edit] Metabolism

PAHs.png

[edit] Non - ligninolytic fungi

Class Genus
Zygomycetes cunninghamella blakesleeana , M verrucosa
C.ehinulata ,Mucor racemosus
C.elgans 외 3 Genus
Ascomycetes Cryphonectria parasitica ,Neurospora crassa 외 4 Genus
Blastomycetes Candida krusei , Rhodotorula gutinis 외 5 Genus
Hyphomycetes Aspergillus niger , Monosporium olivaceum 외 30 Genus
Coelomycetes Cinnobolus cesatii , C,sporulosum 외 3 Genus


Reference Potential of Penicillium Species in the Bioremediation

[edit] Ligninolytic fungi(nutrient-limited)

Lignolytic fungi degrade PAHs trough non specific radical oxidation by Extracellular lignolytic enzymes.

  • Extracellular lignolytic enzyme


Oxidation of polycyclic aromatic hydrocarbons by Ligninolytic fungi Ligninolytic fungi.png

reference :Fungal metabolism of polycyclic aromatic hydrocarbons: past, present and future applications in bioremediation

[edit] Known species

  • Phanerochaete chrysosprium
  • Trametes versicolor
Trametes versicolor
  • Pleurotus ostreatus
Pleurotus ostreatus