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PAHs : non polar,hydrophobic organic compounds
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Polycyclic aromatic hydrocarbons (PAHs), also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons, are potent atmospheric pollutants that consist of fused aromatic rings and do not contain heteroatoms or carry substituents. Naphthalene is the simplest example of a PAH. PAHs occur in oil, coal, and tar deposits, and are produced as byproducts of fuel burning (whether fossil fuel or biomass). As a pollutant, they are of concern because some compounds have been identified as carcinogenic, mutagenic, and teratogenic. PAHs are also found in cooked foods. Studies have shown that high levels of PAHs are found, for example, in meat cooked at high temperatures such as grilling or barbecuing, and in smoked fish. They are also found in the interstellar medium, in comets, and in meteorites and are a candidate molecule to act as a basis for the earliest forms of life.
  
  
  
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<gallery>
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Image:Benzo-a-pyrene.png |Benzo-a-pyrene
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Image:naphthalene.png|naphthalene
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</gallery>
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*PAHs 의 구조
  
 
wikipedia:http://en.wikipedia.org/wiki/Polycyclic_aromatic_hydrocarbon
 
wikipedia:http://en.wikipedia.org/wiki/Polycyclic_aromatic_hydrocarbon
  
= metabolism =
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= Metabolism =
  
== Non - lignolytic fungi ==
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[[file:PAHs.png]]
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== Non - ligninolytic fungi ==
  
[[cytochrome P450 monooxygenase]] 와 epoxide hydrolase-catalysed reaction 에 의해 trans-dihydrodiol을 형성
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{|border="1" cellpadding="5" cellspacing="0"
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|-
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|Class || Genus
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|-
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|rowspan="3"|Zygomycetes||cunninghamella blakesleeana , M verrucosa
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|-
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|C.ehinulata ,Mucor racemosus
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|-
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|C.elgans 외 3 Genus
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|-
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|Ascomycetes || Cryphonectria parasitica ,Neurospora crassa 외 4 Genus
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|-
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|Blastomycetes || Candida krusei , Rhodotorula gutinis 외 5 Genus
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|-
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|Hyphomycetes || Aspergillus niger , Monosporium olivaceum 외 30 Genus
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|-
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|Coelomycetes || Cinnobolus cesatii , C,sporulosum 외 3 Genus
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|-
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|}
  
다른 metabolite 는 phenol,quinone,conjugate를 형성 한다.
 
  
==lignolytic fungi ==
 
  
[[extracellular lignolytic enzyme]] 에 의한 non specific radical oxidation 에 의해 분해된다.
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Reference
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Potential of Penicillium Species in the Bioremediation
  
[[file:PAHs.png]]
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==Ligninolytic fungi(nutrient-limited) ==
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Lignolytic fungi degrade PAHs trough non specific radical oxidation by Extracellular lignolytic enzymes.
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* Extracellular lignolytic enzyme
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::*[[Lignin peroxidase]]
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::*[[Manganese peroxidase | Maganese-dependent peroxidase]]
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::*[[Manganese-independent peroxidase]]
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::*[[Laccase]]
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Oxidation of polycyclic aromatic hydrocarbons by Ligninolytic fungi
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[[file:Ligninolytic fungi.png| 600px]]
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reference :Fungal metabolism of polycyclic aromatic hydrocarbons: past,
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present and future applications in bioremediation
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=== Known species  ===
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* ''Phanerochaete chrysosprium''
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* ''Trametes versicolor''
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::[[KUC Trametes versicolor | Trametes versicolor ]]
  
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*''Pleurotus ostreatus''
  
출처 :Potential of Penicillium Species in the Bioremediation Field
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::[[KUC Pleurotus ostreatus | Pleurotus ostreatus ]]

Latest revision as of 16:31, 8 April 2013

Contents

Polycyclic aromatic hydrocarbons (PAHs), also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons, are potent atmospheric pollutants that consist of fused aromatic rings and do not contain heteroatoms or carry substituents. Naphthalene is the simplest example of a PAH. PAHs occur in oil, coal, and tar deposits, and are produced as byproducts of fuel burning (whether fossil fuel or biomass). As a pollutant, they are of concern because some compounds have been identified as carcinogenic, mutagenic, and teratogenic. PAHs are also found in cooked foods. Studies have shown that high levels of PAHs are found, for example, in meat cooked at high temperatures such as grilling or barbecuing, and in smoked fish. They are also found in the interstellar medium, in comets, and in meteorites and are a candidate molecule to act as a basis for the earliest forms of life.



  • PAHs 의 구조

wikipedia:http://en.wikipedia.org/wiki/Polycyclic_aromatic_hydrocarbon

[edit] Metabolism

PAHs.png

[edit] Non - ligninolytic fungi

Class Genus
Zygomycetes cunninghamella blakesleeana , M verrucosa
C.ehinulata ,Mucor racemosus
C.elgans 외 3 Genus
Ascomycetes Cryphonectria parasitica ,Neurospora crassa 외 4 Genus
Blastomycetes Candida krusei , Rhodotorula gutinis 외 5 Genus
Hyphomycetes Aspergillus niger , Monosporium olivaceum 외 30 Genus
Coelomycetes Cinnobolus cesatii , C,sporulosum 외 3 Genus


Reference Potential of Penicillium Species in the Bioremediation

[edit] Ligninolytic fungi(nutrient-limited)

Lignolytic fungi degrade PAHs trough non specific radical oxidation by Extracellular lignolytic enzymes.

  • Extracellular lignolytic enzyme


Oxidation of polycyclic aromatic hydrocarbons by Ligninolytic fungi Ligninolytic fungi.png

reference :Fungal metabolism of polycyclic aromatic hydrocarbons: past, present and future applications in bioremediation

[edit] Known species

  • Phanerochaete chrysosprium
  • Trametes versicolor
Trametes versicolor
  • Pleurotus ostreatus
Pleurotus ostreatus